Match List-I with List-II.

List-I List-II
A. Haber process I. Fe catalyst
B. Wacker oxidation II. PdCl₂
C. Wilkinson catalyst III. [(PPh₃)₃RhCl]
D. Ziegler catalyst IV. TiCl₄ with Al(CH₃)₃

Choose the correct answer from the options given below:

This question was previously asked in
NEET 2025 Official Paper (Held On: 04 May, 2025)
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  1. A-I, B-II, C-IV, D-III
  2. A-II, B-III, C-I, D-IV
  3. A-I, B-II, C-III, D-IV 
  4. A-I, B-IV, C-III, D-II 

Answer (Detailed Solution Below)

Option 3 : A-I, B-II, C-III, D-IV 
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Detailed Solution

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CONCEPT:

Catalysts and their Applications

  • A catalyst is a substance that speeds up a chemical reaction without being consumed in the process.
  • Different reactions require specific catalysts to enhance the rate of reaction or achieve desired selectivity.

EXPLANATION:

  • In the given problem, we need to match the catalysts in List-I with their corresponding reactions or components in List-II:
    • A. Haber Process: This is the industrial process to synthesize ammonia (NH₃) from nitrogen (N₂) and hydrogen (H₂). The catalyst used is iron (Fe). Hence, A matches with I.
    • B. Wacker Oxidation: This process involves the oxidation of alkenes (e.g., ethylene) to aldehydes or ketones using palladium chloride (PdCl₂) as the catalyst. Hence, B matches with II.
    • C. Wilkinson Catalyst: This is a homogeneous catalyst [(PPh₃)₃RhCl] used for hydrogenation reactions in organic chemistry. Hence, C matches with III.
    • D. Ziegler Catalyst: This catalyst (a combination of TiCl₄ and Al(CH₃)₃) is used for polymerization of alkenes to produce polyethylene. Hence, D matches with IV.

Correct Answer: Option 3) A-I, B-II, C-III, D-IV

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