Question
Download Solution PDFThe correct name of the reaction
is
This question was previously asked in
UP LT Grade Teacher (Science) 2018 Official Paper
Answer (Detailed Solution Below)
Option 1 : Knoevenagel reaction
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UP LT Grade General Knowledge Subject Test 1
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Detailed Solution
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CONCEPT:
Knoevenagel Reaction
- The Knoevenagel reaction is a base-catalyzed condensation reaction between an aldehyde (or ketone) and a compound containing an active methylene group (such as diethyl malonate).
- It typically results in the formation of an α,β-unsaturated compound through the elimination of water.
- In this reaction, the base deprotonates the methylene group, forming a carbanion, which then attacks the carbonyl carbon of the aldehyde.
EXPLANATION:
- In the given reaction, benzaldehyde (C6H5CHO) reacts with diethyl malonate (CH2(COOC2H5)2) in the presence of a base.
- The reaction forms an α,β-unsaturated diester as the product, which is a characteristic product of the Knoevenagel condensation.
- The other options are incorrect:
- Wittig reaction: Forms alkenes using phosphonium ylides, not applicable here.
- Aldol condensation: Involves carbonyl compounds reacting with each other, not an active methylene compound.
- Cannizzaro reaction: Occurs in aldehydes without alpha hydrogens and involves oxidation-reduction, not observed here.
Therefore, the correct answer is Option 1: Knoevenagel reaction.
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