The correct name of the reaction

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UP LT Grade Teacher (Science) 2018 Official Paper
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  1. Knoevenagel reaction
  2. Wittig reaction
  3.  Aldol condensation
  4.  Cannizzaro reaction

Answer (Detailed Solution Below)

Option 1 : Knoevenagel reaction
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CONCEPT:

Knoevenagel Reaction

  • The Knoevenagel reaction is a base-catalyzed condensation reaction between an aldehyde (or ketone) and a compound containing an active methylene group (such as diethyl malonate).
  • It typically results in the formation of an α,β-unsaturated compound through the elimination of water.
  • In this reaction, the base deprotonates the methylene group, forming a carbanion, which then attacks the carbonyl carbon of the aldehyde.

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EXPLANATION:

  • In the given reaction, benzaldehyde (C6H5CHO) reacts with diethyl malonate (CH2(COOC2H5)2) in the presence of a base.
  • The reaction forms an α,β-unsaturated diester as the product, which is a characteristic product of the Knoevenagel condensation.
  • The other options are incorrect:
    • Wittig reaction: Forms alkenes using phosphonium ylides, not applicable here.
    • qImage686e61424db1619eaf357cb1
    • Aldol condensation: Involves carbonyl compounds reacting with each other, not an active methylene compound.
    • qImage686e61424db1619eaf357cb3
    • Cannizzaro reaction: Occurs in aldehydes without alpha hydrogens and involves oxidation-reduction, not observed here.
    • qImage686e61434db1619eaf357cb5

Therefore, the correct answer is Option 1: Knoevenagel reaction.

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