The major product formed in the following reaction is

This question was previously asked in
CSIR-UGC (NET) Chemical Science: Held on (15 Dec 2019)
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Answer (Detailed Solution Below)

Option 3 :
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10 Qs. 20 Marks 15 Mins

Detailed Solution

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Concept:

Stetter reaction: The aldehyde is converted from an electrophile to a nucleophile under the reaction conditions. This is accomplished by activation from some catalyst - either cyanide (CN) or thiazolium salt.

→ The active catalyst can be described as the combination of two contributing resonance forms - an ylide or a carbene, both of which portray the nucleophilic character at carbon.

→ The thiazolium ylide or CN can then add into the aldehyde substrate, forming a cyanohydrin in the case of CN or the Breslow intermediate in the case of thiazolium salt.

Explanation:

Conclusion:
The correct answer is option 3.

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