Question
Download Solution PDFThe temperature dependence of a reaction is given by K = AT2exp(-Eo/RT).
The activation energy (Ea) of the reaction is given by -
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Arrhenius Equation and Modified Temperature Dependence
- The Arrhenius equation describes how the rate constant \(K \) depends on temperature, usually in the form \(K = A \exp(-E_a/RT) \), where \(E_a \) is the activation energy.
- In the modified equation \(K = AT^2 \exp(-E_0/RT)\), the \(T^2\) term accounts for an additional temperature dependency, but \(E_0\) still represents the activation energy barrier.
- The activation energy \(E_a\) is the energy required to start the reaction, which in this case is given directly by \(E_0\).
EXPLANATION:
- The form of the equation \(K = AT^2 \exp(-E_0/RT\)) suggests that despite the additional \(T^2 \) factor, the exponential term controls the temperature dependence of the reaction rate.
- The activation energy \(E_a\) is thus directly given by \(E_0\), which is the energy required for the reaction to occur.
CONCLUSION:
The correct answer is: \(E_0\)
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