The temperature dependence of a reaction is given by K = AT2exp(-Eo/RT).
The activation energy (Ea) of the reaction is given by -

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HPSC Assistant Professor 2018 Chemistry (Official Paper)
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  1. \(\mathrm{E}_0\)
  2. \(\mathrm{E}_0+1/2\mathrm{RT}\)
  3. \(2\mathrm{E}_0+\mathrm{RT}\)
  4. \(\mathrm{E}_0+2\mathrm{RT}\)

Answer (Detailed Solution Below)

Option 1 : \(\mathrm{E}_0\)
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Detailed Solution

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CONCEPT:

Arrhenius Equation and Modified Temperature Dependence

  • The Arrhenius equation describes how the rate constant \(K \) depends on temperature, usually in the form \(K = A \exp(-E_a/RT) \), where \(E_a \) is the activation energy.
  • In the modified equation  \(K = AT^2 \exp(-E_0/RT)\), the  \(T^2\)  term accounts for an additional temperature dependency, but \(E_0\) still represents the activation energy barrier.
  • The activation energy \(E_a\) is the energy required to start the reaction, which in this case is given directly by \(E_0\).

EXPLANATION:

  • The form of the equation \(K = AT^2 \exp(-E_0/RT\)) suggests that despite the additional \(T^2 \) factor, the exponential term controls the temperature dependence of the reaction rate.
  • The activation energy \(E_a\) is thus directly given by \(E_0\), which is the energy required for the reaction to occur.

CONCLUSION:

The correct answer is: \(E_0\) 

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