There is desorption of physical adsorption when: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Temperature increases 
  2. Pressure increases 
  3. Temperature decreases 
  4. Concentration increases 

Answer (Detailed Solution Below)

Option 1 : Temperature increases 
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Detailed Solution

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CONCEPT:

Physical Adsorption

  • Physical adsorption occurs due to weak intermolecular forces like Van der Waals forces between the adsorbate and adsorbent.
  • This type of adsorption is generally reversible and is influenced by temperature and pressure.
  • Desorption in physical adsorption refers to the process where the adsorbed particles are released from the surface of the adsorbent.

EXPLANATION:

  • Physical adsorption is highly dependent on temperature:
    • When the temperature increases, the kinetic energy of the adsorbed molecules increases, leading to the breaking of weak intermolecular forces between the adsorbate and adsorbent.
    • This results in desorption of the adsorbed particles.
  • Pressure also plays a role in physical adsorption:
    • Increasing pressure usually favors adsorption, but it does not directly cause desorption.
  • Thus, desorption occurs primarily when the temperature increases.

Therefore, the correct answer is Temperature increases.

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