CH3COCl \(\xrightarrow[BaSO_4]{Pd, H_2}\) X; then X is?

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HP TGT (Non-Medical) TET 2018 Official Paper
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  1. CH3CHO
  2. CH3CH2CHO

  3. CH3COCH3
  4. CH3COOH

Answer (Detailed Solution Below)

Option 1 : CH3CHO
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HP JBT TET 2021 Official Paper
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Detailed Solution

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Rosenmund reaction: The Rosenmund reaction is a hydrogenation process where molecular hydrogen reacts with the acetyl chloride in the presence of catalyst – palladium on barium sulfate. 

  • The barium sulfate reduces the activity of the palladium due to its low surface area, thereby preventing over-reduction.
  • This reaction is used in the preparation of aldehyde from acyl chloride.

F1  Prakash 03-12-21 Savita D1

Additional Information

  • F1  Prakash 03-12-21 Savita D2
  • Acetyl chloride is produced in the laboratory by the reaction of acetic acid with chlorodehydrating agents such as PCl3, PCl5, SO2Cl2, phosgene, or SOCl2

CH3COOH + PCl5 ------------> CH3COCl 

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