CO₂ when passed in excess, in lime water turns colourless again because of:

Explanation:

• Calcium hydroxide is sparingly soluble in water producing an alkaline solution known as limewater.
• Calcium Carbonate is a chemical compound found commonly in rocks as minerals and is the main component of pearls and the shells of marine organisms, eggs, etc.
• When carbon dioxide gas is passed through or over limewater, it turns milky due to the formation of calcium carbonate.
• In the chemical reaction it can be shown as :

\(\rm \underset{Lime\ water}{Ca (OH)_2} \ (aq) \ + \ \underset{Carbon \ Dioxide}{CO_2 \ (g) }\ \longrightarrow \ \underset{Calcium \ Carbonate}{CaCO_3 \ (g)}\)Ca(OH)2

• However, when an excess of CO2 ​is passed through this solution, the milkiness disappears. This is due to the formation of calcium bicarbonate which is colorless and soluble in water.

​\(\rm \underset{Lime\ water}{Ca (OH)_2} \ (aq) \ + \ \underset{Carbon \ Dioxide}{CO_2 \ (g) }\ \longrightarrow \ \underset{Calcium \ Carbonate}{CaCO_3 \ (g)}\)​\(\rm \underset{Lime\ water}{Ca CO_3} \ (aq) \ + \ \underset{Carbon \ Dioxide}{CO_2 \ (g) }\ \longrightarrow \ \underset{Calcium \ Carbonate}{Ca(HCO_3)_2 \ (g)}\)Lime water (aq) + CO2 (g)Carbon Dioxide ⟶ CaCO3 (g)Calcium Carbonate\(\rm \underset{Calcium\ Carbonate}{Ca CO_3} \ \ +H_2O+ \ \underset{Carbon \ Dioxide}{CO_2 \ (g) } \ \longrightarrow \ \underset{Calcium \ bi\ Carbonate}{Ca(HCO_3)_2 \ (g)}\)

Additional Information Reaction involved-

CaCO₃ + 2HCl →  CaCl₂ + CO₂ + H₂O

• The evolved gas is carbon dioxide which then passes through lime water and turns it milky.

Ca(OH)₂ + CO₂ → H₂O + CaCO₃  

• Due to formation of these compounds
• when excess CO₂ is passed

CaCO₃ + H₂O + CO₂ →  Ca(HCO₃)₂ 

• Bicarbonate is formed which again clears the solution

Mistake Points

•  Do not confuse Calcium carbonate and calcium bicarbonate.
• One produces white colour while the other makes it colourless.