The formation of five oxides of nitrogen is an example of:

  1. Law of multiple proportion
  2. Law of conservation of mass
  3. Law of reciprocal proportions
  4. Law of gaseous volume

Answer (Detailed Solution Below)

Option 1 : Law of multiple proportion
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Concept:

Law of multiple proportions:

  • When two or more compounds are formed by the combination of two elements, the weight of one element that combines with the other is in simple ratios of whole numbers.
  • It was formulated by Dalton.

Law of reciprocal proportion:

  • When two different elements combine with the same mass of a third element, then their masses are either same or in a simple ratio of whole numbers.
  • When hydrogen and oxygen combine with Carbon to form CH4 and CO2 respectively, their masses are in a ratio 1: 8.

Law of conservation of mass:

  • Mass in an isolated system can neither be created nor destroyed.
  • During a chemical process, the mass of the elements is the same as before after the reaction.

Explanation:

The five oxides of Nitrogen and the weight ratio of the elements are:

Compound

Nitrogen

Oxygen

Ratio with a fixed mass of N

     

N

O

N2O

28

16

14

8

NO

14

16

14

16

N2O3

28

48

14

24

NO2

14

32

14

32

N2O5

28

80

14

40

 

  • When oxides of nitrogen are formed with oxygen, the masses of oxygen are 8g,16g, 24g, 32g, 40etc. the ratio is 1: 2 : 3: 4: 5.


Hence, the formation of five oxides of nitrogen is an example of the Law of multiple proportions.

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