The ‘Law of Octaves' was proposed by ______. 

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  1. Johann Wolfgang Döbereiner 
  2. Henry Moseley 
  3. John Newlands 
  4. Dmitri Ivanovich Mendeléev

Answer (Detailed Solution Below)

Option 3 : John Newlands 
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The correct answer is John Newlands.

Key Points

  • John Newlands was an English chemist who proposed the 'Law of Octaves' in 1864.
  • He observed that when elements are arranged in order of increasing atomic mass, every eighth element had properties similar to the first.
  • This pattern was one of the earliest attempts to classify the elements and showed a periodicity in their properties.
  • Newlands' Law of Octaves was initially not accepted by the scientific community, but it laid the groundwork for the development of the modern periodic table.

Additional Information

  • Periodic Table:
    • The modern periodic table arranges elements by increasing atomic number, which is the number of protons in an atom's nucleus.
    • Elements with similar chemical properties are grouped in columns known as groups or families.
    • The periodic table is divided into metals, nonmetals, and metalloids based on their properties.
  • Mendeleev's Periodic Table:
    • Dmitri Mendeleev, a Russian chemist, published a more comprehensive periodic table in 1869.
    • Mendeleev's table left gaps for elements that were yet to be discovered, predicting their properties based on periodic trends.
    • His periodic table was widely accepted because it could explain the properties of known elements and predict new ones.
  • Henry Moseley:
    • Henry Moseley, an English physicist, discovered the atomic number of elements in 1913 through X-ray spectroscopy.
    • Moseley's work led to the reorganization of the periodic table based on atomic number rather than atomic mass.
  • Döbereiner's Triads:
    • Johann Wolfgang Döbereiner, a German chemist, identified groups of three elements (triads) with similar chemical properties in 1829.
    • The middle element of each triad had properties that were approximately an average of the other two.
    • Döbereiner's triads were an early attempt to classify elements based on their properties.
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