What is the NaCl lattice energy content?

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MP Excise Constable Official paper (Held On: 20 Feb 2023 Shift 3)
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  1. 788 KJ mol-1
  2. 688 KJ mol-1
  3. 588 KJ mol-1
  4. 488 KJ mol-1

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Option 1 : 788 KJ mol-1
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The correct answer is NaCl lattice energy content is 788 KJ mol-1.

Key Points

  • The lattice energy of NaCl is approximately 788 KJ mol-1, which is a measure of the strength of the bonds in an ionic compound.
  • Lattice energy is defined as the energy required to separate one mole of a solid ionic compound into its gaseous ions.
  • High lattice energy indicates a strong attraction between the ions in a compound, contributing to high melting and boiling points.
  • NaCl, or table salt, forms a crystalline structure where each Na+ ion is surrounded by six Cl- ions and vice versa.
  • Lattice energy values are derived from the Born-Haber cycle, a theoretical model used to analyze the formation of ionic compounds.

Additional Information

  • Born-Haber Cycle
    • The Born-Haber cycle is a thermodynamic cycle used to calculate lattice energy by combining enthalpy changes associated with the formation of an ionic solid from its constituent elements.
    • It incorporates ionization energy, electron affinity, and enthalpy of sublimation, among other factors.
  • Ionic Compounds
    • Ionic compounds consist of positively charged cations and negatively charged anions held together by electrostatic forces.
    • Examples include NaCl, MgO, and CaF2.
  • Factors Affecting Lattice Energy
    • The magnitude of lattice energy depends on the charge and size of the ions: higher charges and smaller ionic radii result in greater lattice energy.
    • Lattice energy also affects the solubility, hardness, and melting point of ionic compounds.
  • Applications of NaCl
    • NaCl is widely used in food seasoning and preservation, de-icing roads, and in the chemical industry for the production of chlorine and sodium hydroxide.
    • It is also used in water softening processes and as a raw material in various industrial processes.
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